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Navy hopes to make jet fuel from seawater

By extracting dissolved carbon dioxide from seawater and combining it with hydrogen stripped from water molecules, chemists hope to secure a cheap and steady fuel source
/ Source: Discovery Channel

The U.S. Navy could soon be sailing through an ocean of jet fuel if new research proves economical.

By extracting dissolved carbon dioxide from seawater and combining it with hydrogen stripped from water molecules, Navy chemists hope to one day secure a cheap and steady fuel source for its fleet of jets.

"The U.S. Navy is surrounded by seawater and the Navy needs jet fuel," said Robert Dorner, a scientist at the Naval Research Laboratory in Washington, D.C. who works on the technology.

"In the seawater you have CO2 and you have hydrogen. The question is how do you convert that into jet fuel."

The answer, according to Dorner, is a modified version of the chemical reaction known as the Fischer-Tropsch process.

Typically Fischer-Tropsch starts with carbon monoxide and hydrogen and, using metal catalysts and heat, ends with a mixture of methane, waxes and synthesis gas (syngas), which can then produce fuel or plastic.

Fischer-Tropsch is expensive and energy-intensive, which often limits its usefulness. One of the few times it has proven economical was using solid coal to produce liquid fuel for World War II Germany.

Instead of coal, Dorner and his colleagues want to use the carbon dioxide dissolved in seawater (140 times the amount found in the atmosphere) and hydrogen stripped from water as the base materials for the reaction.

They also want to change the metal catalysts, switching from cobalt, which produces mostly methane, to iron, which drops methane production by 70 percent and increases the amount of syngas produced.

Producing syngas instead of methane more efficiently is significant, but it's not jet fuel. One additional step is necessary to get jet fuel. During the next few weeks Dorner and his colleagues will take the final step, turning syngas into actual jet fuel.

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The results of those experiments will help determine whether or not their modified version of the Fischer-Tropsch process is economical for the U.S. Navy.

"It's still a very energy-intensive process," said Dorner. "A lot of work remains to be done. We haven't even really looked at building an actual pilot plant yet."

Assuming the process is economical, Dorner doesn't expect every aircraft carrier in the fleet will be equipped with the technology.

Instead the various pumps and energy sources required to turn seawater into jet fuel would be installed on a separate ship that uses the heat difference in the water column to help power the reaction, although this is speculation, says Dorner.

The economics of turning seawater into jet fuel still need to be demonstrated, said Jean-Michel Lavoie, a scientist at Sherbrooke University in Quebec, Canada. But, he adds, the idea is appealing because it doesn't use drinkable water and there are massive amounts of raw materials to work with.

With cheap oil still readily available, especially in the United States, it probably won't be practical for several years.

"But one thing is for sure," says Lavoie. "The idea of using seawater as a medium for CO2 transportation is a good one and could be beneficial both on the energy as well as environmental point of view."